D | 2012-10-17 | Huracán Valencia |  | 1-2 |  | Alavés | 3R | ||
E | 2012-09-12 | Huracán Valencia | | 1-1(4-2 pen.) |  | Albacete | 2R |
D | 2012-11-28 | Barcelona |  | 3-1 | | Alavés | 4R | ||
D | 2012-10-30 | Alavés | | 0-3 | | Barcelona | 4R | ||
V | 2012-10-17 | Huracán Valencia | | 1-2 | | Alavés | 3R | ||
V | 2012-09-12 | Alavés | | 2-1 |  | At. Sanluqueño | 2R | ||
V | 2012-08-29 | Catarroja CF |  | 0-2 | | Alavés | 1R |
